data_NDE
#

_chem_comp.id                                   NDE
_chem_comp.name                                 "ADENOSINE 5'-(TRIHYDROGEN DIPHOSPHATE) P'-5'-ESTER WITH 3-(AMINOCARBONYL)-4-(1-HYDROXYL-2-OXO-3-PHOSPHONOOXY-PROPYL)-1-BETA-D-RIBOFURANOSYLPYRIDINIUM INNER SALT"
_chem_comp.type                                 NON-POLYMER
_chem_comp.pdbx_type                            HETAIN
_chem_comp.formula                              "C24 H32 N7 O20 P3"
_chem_comp.mon_nstd_parent_comp_id              ?
_chem_comp.pdbx_synonyms                        "NAD WITH (1-HYDROXYL-2-OXO-3-PHOSPHONOOXY-PROPANE)"
_chem_comp.pdbx_formal_charge                   0
_chem_comp.pdbx_initial_date                    2002-11-11
_chem_comp.pdbx_modified_date                   2021-03-01
_chem_comp.pdbx_ambiguous_flag                  N
_chem_comp.pdbx_release_status                  REL
_chem_comp.pdbx_replaced_by                     ?
_chem_comp.pdbx_replaces                        ?
_chem_comp.formula_weight                       831.467
_chem_comp.one_letter_code                      ?
_chem_comp.three_letter_code                    NDE
_chem_comp.pdbx_model_coordinates_details       ?
_chem_comp.pdbx_model_coordinates_missing_flag  Y
_chem_comp.pdbx_ideal_coordinates_details       ?
_chem_comp.pdbx_ideal_coordinates_missing_flag  N
_chem_comp.pdbx_model_coordinates_db_code       1N1E
_chem_comp.pdbx_subcomponent_list               ?
_chem_comp.pdbx_processing_site                 RCSB
#   #
loop_
_chem_comp_atom.comp_id
_chem_comp_atom.atom_id
_chem_comp_atom.alt_atom_id
_chem_comp_atom.type_symbol
_chem_comp_atom.charge
_chem_comp_atom.pdbx_align
_chem_comp_atom.pdbx_aromatic_flag
_chem_comp_atom.pdbx_leaving_atom_flag
_chem_comp_atom.pdbx_stereo_config
_chem_comp_atom.model_Cartn_x
_chem_comp_atom.model_Cartn_y
_chem_comp_atom.model_Cartn_z
_chem_comp_atom.pdbx_model_Cartn_x_ideal
_chem_comp_atom.pdbx_model_Cartn_y_ideal
_chem_comp_atom.pdbx_model_Cartn_z_ideal
_chem_comp_atom.pdbx_component_atom_id
_chem_comp_atom.pdbx_component_comp_id
_chem_comp_atom.pdbx_ordinal
NDE  O7N   NO7   O   0  1  N  N  N  27.612  18.620  -15.613   -5.883   0.314   0.065  O7N   NDE   1  
NDE  C7N   NC7   C   0  1  N  N  N  28.370  18.307  -16.531   -4.908  -0.171  -0.534  C7N   NDE   2  
NDE  N7N   NN7   N   0  1  N  N  N  28.028  17.270  -17.293   -4.717   0.059  -1.893  N7N   NDE   3  
NDE  C3N   NC3   C   0  1  Y  N  N  29.616  19.063  -16.767   -3.917  -0.978   0.161  C3N   NDE   4  
NDE  C4N   NC4   C   0  1  Y  N  N  29.959  20.272  -15.897   -4.036  -2.361   0.260  C4N   NDE   5  
NDE  C5N   NC5   C   0  1  Y  N  N  31.074  21.096  -16.458   -3.065  -3.095   0.934  C5N   NDE   6  
NDE  C6N   NC6   C   0  1  Y  N  N  31.991  20.537  -17.259   -1.990  -2.422   1.497  C6N   NDE   7  
NDE  C2N   NC2   C   0  1  Y  N  N  30.408  18.622  -17.783   -2.820  -0.359   0.744  C2N   NDE   8  
NDE  N1N   NN1   N   1  1  Y  N  N  31.669  19.317  -17.982   -1.890  -1.084   1.392  N1N   NDE   9  
NDE  C1D   NC1*  C   0  1  N  N  R  32.628  18.846  -18.985   -0.729  -0.392   2.006  C1D   NDE  10  
NDE  C2D   NC2*  C   0  1  N  N  R  33.189  17.448  -18.810    0.394  -0.237   0.995  C2D   NDE  11  
NDE  O2D   NO2*  O   0  1  N  N  N  34.260  17.507  -17.900    1.187  -1.402   0.903  O2D   NDE  12  
NDE  C3D   NC3*  C   0  1  N  N  S  33.591  17.087  -20.249    1.147   0.950   1.561  C3D   NDE  13  
NDE  O3D   NO3*  O   0  1  N  N  N  34.937  17.457  -20.467    1.951   0.524   2.661  O3D   NDE  14  
NDE  O4D   NO4*  O   0  1  N  N  N  31.969  18.813  -20.227   -1.059   0.936   2.452  O4D   NDE  15  
NDE  C4D   NC4*  C   0  1  N  N  R  32.730  17.992  -21.130    0.018   1.830   2.089  C4D   NDE  16  
NDE  C5D   NC5*  C   0  1  N  N  N  31.681  17.276  -21.940   -0.504   2.814   1.051  C5D   NDE  17  
NDE  O5D   NO5*  O   0  1  N  N  N  31.138  16.312  -21.073   -1.552   3.577   1.624  O5D   NDE  18  
NDE  PN    NP    P   0  1  N  N  N  29.572  15.980  -21.028   -2.296   4.718   0.718  PN    NDE  19  
NDE  O1N   NO1   O   0  1  N  N  N  29.206  15.911  -19.574   -3.558   5.143   1.436  O1N   NDE  20  
NDE  O2N   NO2   O  -1  1  N  N  N  28.806  16.888  -21.983   -1.280   5.747   0.272  O2N   NDE  21  
NDE  PA    AP    P   0  1  N  N  S  28.251  13.239  -22.141   -3.495   4.192  -1.937  PA    NDE  22  
NDE  O1A   AO1   O   0  1  N  N  N  28.890  12.143  -21.393   -2.818   5.247  -2.763  O1A   NDE  23  
NDE  O3    O3    O   0  1  N  N  N  29.256  14.222  -21.583   -2.714   3.809  -0.573  O3    NDE  24  
NDE  O2A   AO2   O   0  1  N  N  N  27.204  14.070  -21.491   -3.656   2.765  -2.682  O2A   NDE  25  
NDE  O5B   AO5*  O   0  1  N  N  N  28.641  13.441  -23.657   -4.995   4.566  -1.457  O5B   NDE  26  
NDE  C5B   AC5*  C   0  1  N  N  N  29.552  12.636  -24.360   -5.736   3.649  -0.671  C5B   NDE  27  
NDE  C4B   AC4*  C   0  1  N  N  R  29.961  13.479  -25.535   -7.098   4.257  -0.368  C4B   NDE  28  
NDE  O4B   AO4*  O   0  1  N  N  N  31.084  12.780  -26.125   -7.792   4.467  -1.620  O4B   NDE  29  
NDE  C1B   AC1*  C   0  1  N  N  R  30.702  12.319  -27.398   -8.945   3.605  -1.663  C1B   NDE  30  
NDE  C2B   AC2*  C   0  1  N  N  R  29.188  12.300  -27.426   -8.722   2.547  -0.593  C2B   NDE  31  
NDE  O2B   AO2*  O   0  1  N  N  N  28.772  12.368  -28.757   -9.940   2.000  -0.130  O2B   NDE  32  
NDE  C3B   AC3*  C   0  1  N  N  S  28.893  13.564  -26.611   -7.986   3.341   0.468  C3B   NDE  33  
NDE  O3B   AO3*  O   0  1  N  N  N  29.113  14.692  -27.411   -8.919   4.142   1.195  O3B   NDE  34  
NDE  N9A   AN9   N   0  1  Y  N  N  31.362  11.039  -27.551   -9.106   3.064  -3.010  N9A   NDE  35  
NDE  C8A   AC8   C   0  1  Y  N  N  31.145   9.891  -26.836   -8.096   2.764  -3.887  C8A   NDE  36  
NDE  N7A   AN7   N   0  1  Y  N  N  31.952   8.941  -27.267   -8.551   2.292  -5.029  N7A   NDE  37  
NDE  C5A   AC5   C   0  1  Y  N  N  32.742   9.472  -28.277   -9.916   2.285  -4.887  C5A   NDE  38  
NDE  C6A   AC6   C   0  1  Y  N  N  33.777   8.956  -29.080  -10.946   1.901  -5.740  C6A   NDE  39  
NDE  N6A   AN6   N   0  1  N  N  N  34.166   7.685  -28.940  -10.666   1.406  -7.026  N6A   NDE  40  
NDE  C4A   AC4   C   0  1  Y  N  N  32.367  10.788  -28.446  -10.282   2.762  -3.639  C4A   NDE  41  
NDE  N3A   AN3   N   0  1  Y  N  N  32.972  11.556  -29.367  -11.526   2.897  -3.154  N3A   NDE  42  
NDE  C2A   AC2   C   0  1  Y  N  N  33.948  11.050  -30.134  -12.435   2.494  -4.068  C2A   NDE  43  
NDE  N1A   AN1   N   0  1  Y  N  N  34.348   9.769  -29.997  -12.228   2.010  -5.316  N1A   NDE  44  
NDE  P     P     P   0  1  N  N  N  31.261  15.254  -13.397   -8.236  -3.238   3.864  P     NDE  45  
NDE  O1P   O1P   O   0  1  N  N  N  32.006  15.287  -14.706   -8.983  -4.212   4.728  O1P   NDE  46  
NDE  O2P   O2P   O   0  1  N  N  N  32.013  14.748  -12.210   -9.146  -2.104   3.156  O2P   NDE  47  
NDE  O3P   O3P   O   0  1  N  N  N  29.820  14.912  -13.511   -7.099  -2.380   4.628  O3P   NDE  48  
NDE  O1    O1    O   0  1  N  N  N  31.231  16.818  -13.023   -7.424  -3.905   2.630  O1    NDE  49  
NDE  C1    C1    C   0  1  N  N  N  30.367  17.666  -13.794   -6.693  -3.059   1.765  C1    NDE  50  
NDE  C2    C2    C   0  1  N  N  N  30.924  19.034  -14.048   -6.008  -3.870   0.681  C2    NDE  51  
NDE  O2    O2    O   0  1  N  N  N  32.121  19.353  -14.066   -6.112  -5.096   0.627  O2    NDE  52  
NDE  C3    C3    C   0  1  N  N  R  29.942  20.100  -14.337   -5.195  -3.081  -0.348  C3    NDE  53  
NDE  O31   O31   O   0  1  N  N  N       ?       ?        ?   -4.718  -3.973  -1.351  O31   NDE  54  
NDE  H71N  NH71  H   0  0  N  N  N  27.167  16.747  -17.130   -3.905  -0.336  -2.354  H71N  NDE  55  
NDE  H72N  NH72  H   0  0  N  N  N  28.656  17.010  -18.053   -5.373   0.614  -2.433  H72N  NDE  56  
NDE  H5N   NH5   H   0  1  N  N  N  31.228  22.172  -16.271   -3.138  -4.174   1.024  H5N   NDE  57  
NDE  H6N   NH6   H   0  1  N  N  N  32.962  21.055  -17.320   -1.198  -2.927   2.036  H6N   NDE  58  
NDE  H2N   NH2   H   0  1  N  N  N  30.057  17.773  -18.393   -2.655   0.712   0.712  H2N   NDE  59  
NDE  H1D   NH1*  H   0  1  N  N  N  33.483  19.554  -18.890   -0.455  -1.010   2.867  H1D   NDE  60  
NDE  H2D   NH2*  H   0  1  N  N  N  32.501  16.680  -18.384   -0.006   0.000   0.003  H2D   NDE  61  
NDE  HO2N  NHO2  H   0  0  N  N  N  34.611  16.631  -17.790    1.511  -1.460  -0.013  HO2N  NDE  62  
NDE  H3D   NH3*  H   0  1  N  N  N  33.463  15.998  -20.454    1.804   1.442   0.840  H3D   NDE  63  
NDE  HO3N  NHO3  H   0  0  N  N  N  35.185  17.233  -21.356    2.515  -0.190   2.327  HO3N  NDE  64  
NDE  H4D   NH4*  H   0  1  N  N  N  33.424  18.513  -21.829    0.312   2.377   2.991  H4D   NDE  65  
NDE  H51N  NH51  H   0  0  N  N  N  30.920  17.954  -22.391   -0.892   2.281   0.178  H51N  NDE  66  
NDE  H52N  NH52  H   0  0  N  N  N  32.063  16.854  -22.898    0.292   3.492   0.732  H52N  NDE  67  
NDE  HOA2  2HOA  H   0  0  N  N  N  26.791  14.777  -21.973   -3.983   2.747  -3.607  HOA2  NDE  68  
NDE  H51A  AH51  H   0  0  N  N  N  30.404  12.266  -23.744   -5.856   2.717  -1.225  H51A  NDE  69  
NDE  H52A  AH52  H   0  0  N  N  N  29.155  11.630  -24.635   -5.197   3.455   0.258  H52A  NDE  70  
NDE  H4B   AH4*  H   0  1  N  N  N  30.171  14.516  -25.184   -6.961   5.236   0.102  H4B   NDE  71  
NDE  H1B   AH1*  H   0  1  N  N  N  31.004  12.950  -28.265   -9.844   4.203  -1.482  H1B   NDE  72  
NDE  H2B   AH2*  H   0  1  N  N  N  28.671  11.400  -27.016   -8.088   1.734  -0.968  H2B   NDE  73  
NDE  HO2A  AHO2  H   0  0  N  N  N  27.822  12.356  -28.774  -10.276   1.411  -0.828  HO2A  NDE  74  
NDE  H3B   AH3*  H   0  1  N  N  N  27.851  13.638  -26.220   -7.446   2.722   1.189  H3B   NDE  75  
NDE  HO3A  AHO3  H   0  0  N  N  N  28.444  14.745  -28.084   -8.534   4.280   2.073  HO3A  NDE  76  
NDE  H8A   AH8   H   0  1  N  N  N  30.416   9.750  -26.020   -7.054   2.910  -3.637  H8A   NDE  77  
NDE  H61A  AH61  H   0  0  N  N  N  34.915   7.311  -29.521   -9.715   1.360  -7.340  H61A  NDE  78  
NDE  H62A  AH62  H   0  0  N  N  N  33.347   7.085  -29.045  -11.423   1.194  -7.648  H62A  NDE  79  
NDE  H2A   AH2   H   0  1  N  N  N  34.428  11.696  -30.887  -13.473   2.568  -3.761  H2A   NDE  80  
NDE  HOP2  2HOP  H   0  0  N  N  N  31.543  14.727  -11.384   -9.789  -1.603   3.701  HOP2  NDE  81  
NDE  HOP3  3HOP  H   0  0  N  N  N  29.350  14.891  -12.685   -7.323  -1.946   5.479  HOP3  NDE  82  
NDE  H11   1H1   H   0  1  N  N  N  30.088  17.172  -14.754   -7.391  -2.359   1.299  H11   NDE  83  
NDE  H12   2H1   H   0  1  N  N  N  29.360  17.735  -13.319   -5.954  -2.509   2.352  H12   NDE  84  
NDE  H31   1H3   H   0  1  N  N  N  30.030  21.139  -13.942   -5.888  -2.387  -0.850  H31   NDE  85  
NDE  H311  1H31  H   0  0  N  N  N  -0.010  -0.104    0.944   -5.345  -4.712  -1.385  H311  NDE  86  
#   #
loop_
_chem_comp_bond.comp_id
_chem_comp_bond.atom_id_1
_chem_comp_bond.atom_id_2
_chem_comp_bond.value_order
_chem_comp_bond.pdbx_aromatic_flag
_chem_comp_bond.pdbx_stereo_config
_chem_comp_bond.pdbx_ordinal
NDE  O7N  C7N   DOUB  N  N   1  
NDE  C7N  N7N   SING  N  N   2  
NDE  C7N  C3N   SING  N  N   3  
NDE  N7N  H71N  SING  N  N   4  
NDE  N7N  H72N  SING  N  N   5  
NDE  C3N  C4N   SING  Y  N   6  
NDE  C3N  C2N   DOUB  Y  N   7  
NDE  C4N  C5N   DOUB  Y  N   8  
NDE  C4N  C3    SING  N  N   9  
NDE  C5N  C6N   SING  Y  N  10  
NDE  C5N  H5N   SING  N  N  11  
NDE  C6N  N1N   DOUB  Y  N  12  
NDE  C6N  H6N   SING  N  N  13  
NDE  C2N  N1N   SING  Y  N  14  
NDE  C2N  H2N   SING  N  N  15  
NDE  N1N  C1D   SING  N  N  16  
NDE  C1D  C2D   SING  N  N  17  
NDE  C1D  O4D   SING  N  N  18  
NDE  C1D  H1D   SING  N  N  19  
NDE  C2D  O2D   SING  N  N  20  
NDE  C2D  C3D   SING  N  N  21  
NDE  C2D  H2D   SING  N  N  22  
NDE  O2D  HO2N  SING  N  N  23  
NDE  C3D  O3D   SING  N  N  24  
NDE  C3D  C4D   SING  N  N  25  
NDE  C3D  H3D   SING  N  N  26  
NDE  O3D  HO3N  SING  N  N  27  
NDE  O4D  C4D   SING  N  N  28  
NDE  C4D  C5D   SING  N  N  29  
NDE  C4D  H4D   SING  N  N  30  
NDE  C5D  O5D   SING  N  N  31  
NDE  C5D  H51N  SING  N  N  32  
NDE  C5D  H52N  SING  N  N  33  
NDE  O5D  PN    SING  N  N  34  
NDE  PN   O1N   DOUB  N  N  35  
NDE  PN   O2N   SING  N  N  36  
NDE  PN   O3    SING  N  N  37  
NDE  PA   O1A   DOUB  N  N  38  
NDE  PA   O3    SING  N  N  39  
NDE  PA   O2A   SING  N  N  40  
NDE  PA   O5B   SING  N  N  41  
NDE  O2A  HOA2  SING  N  N  42  
NDE  O5B  C5B   SING  N  N  43  
NDE  C5B  C4B   SING  N  N  44  
NDE  C5B  H51A  SING  N  N  45  
NDE  C5B  H52A  SING  N  N  46  
NDE  C4B  O4B   SING  N  N  47  
NDE  C4B  C3B   SING  N  N  48  
NDE  C4B  H4B   SING  N  N  49  
NDE  O4B  C1B   SING  N  N  50  
NDE  C1B  C2B   SING  N  N  51  
NDE  C1B  N9A   SING  N  N  52  
NDE  C1B  H1B   SING  N  N  53  
NDE  C2B  O2B   SING  N  N  54  
NDE  C2B  C3B   SING  N  N  55  
NDE  C2B  H2B   SING  N  N  56  
NDE  O2B  HO2A  SING  N  N  57  
NDE  C3B  O3B   SING  N  N  58  
NDE  C3B  H3B   SING  N  N  59  
NDE  O3B  HO3A  SING  N  N  60  
NDE  N9A  C8A   SING  Y  N  61  
NDE  N9A  C4A   SING  Y  N  62  
NDE  C8A  N7A   DOUB  Y  N  63  
NDE  C8A  H8A   SING  N  N  64  
NDE  N7A  C5A   SING  Y  N  65  
NDE  C5A  C6A   DOUB  Y  N  66  
NDE  C5A  C4A   SING  Y  N  67  
NDE  C6A  N6A   SING  N  N  68  
NDE  C6A  N1A   SING  Y  N  69  
NDE  N6A  H61A  SING  N  N  70  
NDE  N6A  H62A  SING  N  N  71  
NDE  C4A  N3A   DOUB  Y  N  72  
NDE  N3A  C2A   SING  Y  N  73  
NDE  C2A  N1A   DOUB  Y  N  74  
NDE  C2A  H2A   SING  N  N  75  
NDE  P    O1P   DOUB  N  N  76  
NDE  P    O2P   SING  N  N  77  
NDE  P    O3P   SING  N  N  78  
NDE  P    O1    SING  N  N  79  
NDE  O2P  HOP2  SING  N  N  80  
NDE  O3P  HOP3  SING  N  N  81  
NDE  O1   C1    SING  N  N  82  
NDE  C1   C2    SING  N  N  83  
NDE  C1   H11   SING  N  N  84  
NDE  C1   H12   SING  N  N  85  
NDE  C2   O2    DOUB  N  N  86  
NDE  C2   C3    SING  N  N  87  
NDE  C3   O31   SING  N  N  88  
NDE  C3   H31   SING  N  N  89  
NDE  O31  H311  SING  N  N  90  
#   #
loop_
_pdbx_chem_comp_descriptor.comp_id
_pdbx_chem_comp_descriptor.type
_pdbx_chem_comp_descriptor.program
_pdbx_chem_comp_descriptor.program_version
_pdbx_chem_comp_descriptor.descriptor
NDE  SMILES_CANONICAL  CACTVS                3.341  "NC(=O)c1c[n+](ccc1[C@@H](O)C(=O)CO[P](O)(O)=O)[C@@H]2O[C@H](CO[P]([O-])(=O)O[P@](O)(=O)OC[C@H]3O[C@H]([C@H](O)[C@@H]3O)n4cnc5c(N)ncnc45)[C@@H](O)[C@H]2O"  
NDE  SMILES            CACTVS                3.341  "NC(=O)c1c[n+](ccc1[CH](O)C(=O)CO[P](O)(O)=O)[CH]2O[CH](CO[P]([O-])(=O)O[P](O)(=O)OC[CH]3O[CH]([CH](O)[CH]3O)n4cnc5c(N)ncnc45)[CH](O)[CH]2O"  
NDE  SMILES_CANONICAL  "OpenEye OEToolkits"  1.5.0  "c1c[n+](cc(c1[C@H](C(=O)COP(=O)(O)O)O)C(=O)N)[C@H]2[C@@H]([C@@H]([C@H](O2)CO[P@@](=O)([O-])O[P@@](=O)(O)OC[C@@H]3[C@H]([C@H]([C@@H](O3)n4cnc5c4ncnc5N)O)O)O)O"  
NDE  SMILES            "OpenEye OEToolkits"  1.5.0  "c1c[n+](cc(c1C(C(=O)COP(=O)(O)O)O)C(=O)N)C2C(C(C(O2)COP(=O)([O-])OP(=O)(O)OCC3C(C(C(O3)n4cnc5c4ncnc5N)O)O)O)O"  
NDE  InChI             InChI                 1.03   "InChI=1S/C24H32N7O20P3/c25-20-14-22(28-7-27-20)31(8-29-14)24-19(37)17(35)13(50-24)6-48-54(44,45)51-53(42,43)47-5-12-16(34)18(36)23(49-12)30-2-1-9(10(3-30)21(26)38)15(33)11(32)4-46-52(39,40)41/h1-3,7-8,12-13,15-19,23-24,33-37H,4-6H2,(H7-,25,26,27,28,38,39,40,41,42,43,44,45)/t12-,13-,15?,16-,17-,18-,19-,23-,24-/m1/s1"  
NDE  InChIKey          InChI                 1.03   IVZPTIKSOMOSEU-WPIGAQFXSA-N  
#
_pdbx_chem_comp_identifier.comp_id          NDE
_pdbx_chem_comp_identifier.type             "SYSTEMATIC NAME"
_pdbx_chem_comp_identifier.program          "OpenEye OEToolkits"
_pdbx_chem_comp_identifier.program_version  1.5.0
_pdbx_chem_comp_identifier.identifier       "[(2R,3S,4R,5R)-5-[3-aminocarbonyl-4-[(1R)-1-hydroxy-2-oxo-3-phosphonooxy-propyl]pyridin-1-ium-1-yl]-3,4-dihydroxy-oxolan-2-yl]methyl [[(2R,3S,4R,5R)-5-(6-aminopurin-9-yl)-3,4-dihydroxy-oxolan-2-yl]methoxy-hydroxy-phosphoryl] phosphate"
#   #
loop_
_pdbx_chem_comp_audit.comp_id
_pdbx_chem_comp_audit.action_type
_pdbx_chem_comp_audit.date
_pdbx_chem_comp_audit.processing_site
NDE  "Create component"   2002-11-11  RCSB  
NDE  "Modify descriptor"  2011-06-04  RCSB  
NDE  "Modify synonyms"    2021-03-01  PDBE  
#
_pdbx_chem_comp_synonyms.ordinal     1
_pdbx_chem_comp_synonyms.comp_id     NDE
_pdbx_chem_comp_synonyms.name        "NAD WITH (1-HYDROXYL-2-OXO-3-PHOSPHONOOXY-PROPANE)"
_pdbx_chem_comp_synonyms.provenance  ?
_pdbx_chem_comp_synonyms.type        ?
##
