data_GN9
# 
_chem_comp.id                                    GN9 
_chem_comp.name                                  "gallinamide A, bound form" 
_chem_comp.type                                  non-polymer 
_chem_comp.pdbx_type                             HETAIN 
_chem_comp.formula                               "C31 H54 N4 O7" 
_chem_comp.mon_nstd_parent_comp_id               ? 
_chem_comp.pdbx_synonyms                         "(2S)-1-{[(2S)-1-({(2S)-5-[(2S)-3-methoxy-2-methyl-5-oxo-2,5-dihydro-1H-pyrrol-1-yl]-5-oxopentan-2-yl}amino)-4-methyl-1-oxopentan-2-yl]amino}-4-methyl-1-oxopentan-2-yl N,N-dimethyl-L-isoleucinate" 
_chem_comp.pdbx_formal_charge                    0 
_chem_comp.pdbx_initial_date                     2020-08-30 
_chem_comp.pdbx_modified_date                    2024-09-27 
_chem_comp.pdbx_ambiguous_flag                   N 
_chem_comp.pdbx_release_status                   REL 
_chem_comp.pdbx_replaced_by                      ? 
_chem_comp.pdbx_replaces                         ? 
_chem_comp.formula_weight                        594.783 
_chem_comp.one_letter_code                       ? 
_chem_comp.three_letter_code                     GN9 
_chem_comp.pdbx_model_coordinates_details        ? 
_chem_comp.pdbx_model_coordinates_missing_flag   N 
_chem_comp.pdbx_ideal_coordinates_details        Corina 
_chem_comp.pdbx_ideal_coordinates_missing_flag   N 
_chem_comp.pdbx_model_coordinates_db_code        7JUJ 
_chem_comp.pdbx_subcomponent_list                ? 
_chem_comp.pdbx_processing_site                  RCSB 
_chem_comp.pdbx_pcm                              Y 
# 
loop_
_chem_comp_atom.comp_id 
_chem_comp_atom.atom_id 
_chem_comp_atom.alt_atom_id 
_chem_comp_atom.type_symbol 
_chem_comp_atom.charge 
_chem_comp_atom.pdbx_align 
_chem_comp_atom.pdbx_aromatic_flag 
_chem_comp_atom.pdbx_leaving_atom_flag 
_chem_comp_atom.pdbx_stereo_config 
_chem_comp_atom.pdbx_backbone_atom_flag 
_chem_comp_atom.pdbx_n_terminal_atom_flag 
_chem_comp_atom.pdbx_c_terminal_atom_flag 
_chem_comp_atom.model_Cartn_x 
_chem_comp_atom.model_Cartn_y 
_chem_comp_atom.model_Cartn_z 
_chem_comp_atom.pdbx_model_Cartn_x_ideal 
_chem_comp_atom.pdbx_model_Cartn_y_ideal 
_chem_comp_atom.pdbx_model_Cartn_z_ideal 
_chem_comp_atom.pdbx_component_atom_id 
_chem_comp_atom.pdbx_component_comp_id 
_chem_comp_atom.pdbx_ordinal 
GN9 C1  C1  C 0 1 N N N N N N 141.416 32.594 34.469 7.573  -3.299 -0.960 C1  GN9 1  
GN9 C2  C2  C 0 1 N N S N N N 140.850 31.868 33.237 6.360  -2.475 -0.523 C2  GN9 2  
GN9 C3  C3  C 0 1 N N N N N N 141.653 30.585 33.008 5.399  -2.316 -1.704 C3  GN9 3  
GN9 C4  C4  C 0 1 N N S N N N 140.701 32.825 32.007 6.823  -1.095 -0.053 C4  GN9 4  
GN9 C5  C5  C 0 1 N N N N N N 141.481 32.456 30.743 5.645  -0.328 0.491  C5  GN9 5  
GN9 C6  C6  C 0 1 N N S N N N 142.566 33.450 28.738 3.725  1.061  0.240  C6  GN9 6  
GN9 O1  O1  O 0 1 N N N N N N 142.225 33.555 30.121 4.769  0.243  -0.351 O1  GN9 7  
GN9 O2  O2  O 0 1 N N N N N N 144.703 33.105 29.541 2.533  0.539  -1.730 O2  GN9 8  
GN9 O3  O3  O 0 1 N N N N N N 145.952 32.364 25.838 -0.723 2.889  0.540  O3  GN9 9  
GN9 O4  O4  O 0 1 N N N N N N 152.151 31.791 25.845 -6.937 1.370  -1.133 O4  GN9 10 
GN9 O5  O5  O 0 1 N N N N N N 151.633 30.068 29.589 -4.877 -0.880 1.513  O5  GN9 11 
GN9 O6  O6  O 0 1 N N N N N N 156.148 31.327 29.102 -8.961 -3.119 1.058  O6  GN9 12 
GN9 C26 C7  C 0 1 N N N N N N 152.707 30.545 29.060 -6.002 -1.118 1.116  C26 GN9 13 
GN9 C25 C8  C 0 1 N N N N N N 153.929 30.548 29.729 -6.773 -2.226 1.522  C25 GN9 14 
GN9 C24 C9  C 0 1 N N N N N N 154.813 31.137 28.812 -7.971 -2.216 0.911  C24 GN9 15 
GN9 C27 C10 C 0 1 N N N N N N 157.119 31.690 28.098 -8.718 -4.220 1.972  C27 GN9 16 
GN9 C23 C11 C 0 1 N N S N N N 154.210 31.558 27.515 -7.985 -0.990 0.024  C23 GN9 17 
GN9 C28 C12 C 0 1 N N N N N N 154.333 33.063 27.280 -8.152 -1.387 -1.444 C28 GN9 18 
GN9 N2  N1  N 0 1 N N N N N N 152.858 31.097 27.848 -6.676 -0.355 0.236  N2  GN9 19 
GN9 C22 C13 C 0 1 N N N N N N 151.873 31.275 26.905 -6.232 0.776  -0.347 C22 GN9 20 
GN9 C21 C14 C 0 1 N N N N N N 150.447 30.895 27.114 -4.857 1.301  -0.022 C21 GN9 21 
GN9 C20 C15 C 0 1 N N N N N N 149.589 31.355 25.942 -4.602 2.586  -0.813 C20 GN9 22 
GN9 C18 C16 C 0 1 N N S N N N 148.611 32.413 26.451 -3.206 3.119  -0.483 C18 GN9 23 
GN9 C19 C17 C 0 1 N N N N N N 149.286 33.566 27.192 -2.998 4.467  -1.176 C19 GN9 24 
GN9 N1  N2  N 0 1 N N N N N N 147.597 31.774 27.270 -2.196 2.167  -0.953 N1  GN9 25 
GN9 C17 C18 C 0 1 N N N N N N 146.338 31.806 26.869 -0.981 2.133  -0.372 C17 GN9 26 
GN9 C12 C19 C 0 1 N N S N N N 145.365 31.098 27.736 0.058  1.154  -0.856 C12 GN9 27 
GN9 C13 C20 C 0 1 N N N N N N 145.164 29.718 27.140 -0.470 -0.273 -0.693 C13 GN9 28 
GN9 C14 C21 C 0 1 N N N N N N 144.021 28.971 27.826 0.531  -1.259 -1.297 C14 GN9 29 
GN9 C16 C22 C 0 1 N N N N N N 143.732 27.656 27.129 0.064  -2.691 -1.025 C16 GN9 30 
GN9 C15 C23 C 0 1 N N N N N N 144.275 28.725 29.315 0.623  -1.032 -2.807 C15 GN9 31 
GN9 N   N3  N 0 1 N N N N N N 144.112 31.823 27.816 1.283  1.314  -0.069 N   GN9 32 
GN9 C11 C24 C 0 1 N N N N N N 143.897 32.776 28.716 2.472  0.952  -0.591 C11 GN9 33 
GN9 C7  C25 C 0 1 N N N N N N 142.627 34.833 28.076 4.183  2.520  0.283  C7  GN9 34 
GN9 C8  C26 C 0 1 N N N N N N 141.296 35.324 27.461 3.138  3.360  1.021  C8  GN9 35 
GN9 C10 C27 C 0 1 N N N N N N 140.522 34.243 26.702 3.093  2.942  2.492  C10 GN9 36 
GN9 C9  C28 C 0 1 N N N N N N 141.470 36.495 26.478 3.513  4.840  0.923  C9  GN9 37 
GN9 O   O7  O 0 1 N N N N N N 141.489 31.332 30.240 5.489  -0.228 1.685  O   GN9 38 
GN9 N3  N4  N 0 1 N N N N N N 139.267 33.052 31.644 7.834  -1.251 1.001  N3  GN9 39 
GN9 C30 C29 C 0 1 N N N N N N 139.160 34.092 30.595 8.259  0.056  1.521  C30 GN9 40 
GN9 C29 C30 C 0 1 N N N N N N 138.443 33.459 32.813 7.339  -2.112 2.083  C29 GN9 41 
GN9 C   C31 C 0 1 N N N N N N 140.556 32.390 35.702 7.126  -4.720 -1.309 C   GN9 42 
GN9 H1  H1  H 0 1 N N N N N N 142.426 32.209 34.674 8.030  -2.836 -1.835 H1  GN9 43 
GN9 H2  H2  H 0 1 N N N N N N 141.472 33.671 34.251 8.299  -3.335 -0.148 H2  GN9 44 
GN9 H3  H3  H 0 1 N N N N N N 139.830 31.554 33.504 5.850  -2.985 0.294  H3  GN9 45 
GN9 H4  H4  H 0 1 N N N N N N 141.686 30.001 33.940 5.070  -3.299 -2.039 H4  GN9 46 
GN9 H5  H5  H 0 1 N N N N N N 141.173 29.988 32.218 4.535  -1.729 -1.392 H5  GN9 47 
GN9 H6  H6  H 0 1 N N N N N N 142.677 30.843 32.701 5.910  -1.806 -2.521 H6  GN9 48 
GN9 H7  H7  H 0 1 N N N N N N 141.097 33.797 32.336 7.254  -0.550 -0.893 H7  GN9 49 
GN9 H8  H8  H 0 1 N N N N N N 141.830 32.830 28.206 3.520  0.713  1.253  H8  GN9 50 
GN9 H9  H9  H 0 1 N N N N N N 154.146 30.182 30.722 -6.447 -2.978 2.226  H9  GN9 51 
GN9 H10 H10 H 0 1 N N N N N N 158.111 31.785 28.564 -7.852 -4.789 1.634  H10 GN9 52 
GN9 H11 H11 H 0 1 N N N N N N 157.152 30.912 27.321 -8.527 -3.828 2.971  H11 GN9 53 
GN9 H12 H12 H 0 1 N N N N N N 156.834 32.650 27.643 -9.592 -4.871 1.998  H12 GN9 54 
GN9 H13 H13 H 0 1 N N N N N N 154.637 30.994 26.672 -8.787 -0.318 0.329  H13 GN9 55 
GN9 H14 H14 H 0 1 N N N N N N 155.377 33.313 27.038 -7.367 -2.090 -1.722 H14 GN9 56 
GN9 H15 H15 H 0 1 N N N N N N 153.682 33.358 26.444 -9.126 -1.856 -1.586 H15 GN9 57 
GN9 H16 H16 H 0 1 N N N N N N 154.029 33.602 28.189 -8.083 -0.498 -2.071 H16 GN9 58 
GN9 H17 H17 H 0 1 N N N N N N 150.079 31.366 28.037 -4.792 1.512  1.045  H17 GN9 59 
GN9 H18 H18 H 0 1 N N N N N N 150.375 29.801 27.207 -4.110 0.554  -0.291 H18 GN9 60 
GN9 H19 H19 H 0 1 N N N N N N 149.032 30.500 25.531 -4.667 2.374  -1.880 H19 GN9 61 
GN9 H20 H20 H 0 1 N Y N N N N 150.229 31.786 25.159 -5.349 3.332  -0.544 H20 GN9 62 
GN9 H21 H21 H 0 1 N N N N N N 148.114 32.843 25.569 -3.111 3.246  0.595  H21 GN9 63 
GN9 H22 H22 H 0 1 N N N N N N 148.523 34.284 27.527 -3.750 5.175  -0.826 H22 GN9 64 
GN9 H23 H23 H 0 1 N N N N N N 149.828 33.173 28.065 -2.004 4.847  -0.941 H23 GN9 65 
GN9 H24 H24 H 0 1 N N N N N N 149.994 34.071 26.518 -3.093 4.340  -2.255 H24 GN9 66 
GN9 H25 H25 H 0 1 N N N N N N 147.847 31.317 28.124 -2.402 1.562  -1.683 H25 GN9 67 
GN9 H26 H26 H 0 1 N N N N N N 145.793 30.988 28.743 0.274  1.344  -1.907 H26 GN9 68 
GN9 H27 H27 H 0 1 N N N N N N 144.932 29.822 26.070 -0.602 -0.493 0.367  H27 GN9 69 
GN9 H28 H28 H 0 1 N N N N N N 146.092 29.139 27.259 -1.428 -0.366 -1.206 H28 GN9 70 
GN9 H29 H29 H 0 1 N N N N N N 143.120 29.597 27.744 1.511  -1.105 -0.846 H29 GN9 71 
GN9 H30 H30 H 0 1 N N N N N N 142.907 27.141 27.643 -0.916 -2.845 -1.476 H30 GN9 72 
GN9 H31 H31 H 0 1 N N N N N N 143.449 27.850 26.084 0.777  -3.394 -1.456 H31 GN9 73 
GN9 H32 H32 H 0 1 N N N N N N 144.631 27.023 27.154 -0.002 -2.853 0.051  H32 GN9 74 
GN9 H33 H33 H 0 1 N N N N N N 144.484 29.682 29.815 1.336  -1.735 -3.238 H33 GN9 75 
GN9 H34 H34 H 0 1 N N N N N N 143.385 28.262 29.767 -0.357 -1.186 -3.259 H34 GN9 76 
GN9 H35 H35 H 0 1 N N N N N N 145.138 28.054 29.434 0.955  -0.012 -3.002 H35 GN9 77 
GN9 H36 H36 H 0 1 N N N N N N 143.383 31.597 27.170 1.239  1.680  0.828  H36 GN9 78 
GN9 H37 H37 H 0 1 N N N N N N 143.379 34.794 27.274 5.137  2.585  0.806  H37 GN9 79 
GN9 H38 H38 H 0 1 N N N N N N 142.940 35.562 28.838 4.299  2.895  -0.734 H38 GN9 80 
GN9 H39 H39 H 0 1 N N N N N N 140.659 35.674 28.287 2.159  3.202  0.568  H39 GN9 81 
GN9 H40 H40 H 0 1 N N N N N N 140.366 33.374 27.358 2.309  3.499  3.004  H40 GN9 82 
GN9 H41 H41 H 0 1 N N N N N N 139.547 34.644 26.386 2.884  1.874  2.560  H41 GN9 83 
GN9 H42 H42 H 0 1 N N N N N N 141.096 33.935 25.816 4.055  3.154  2.960  H42 GN9 84 
GN9 H43 H43 H 0 1 N N N N N N 142.023 37.308 26.970 3.545  5.138  -0.125 H43 GN9 85 
GN9 H44 H44 H 0 1 N N N N N N 142.030 36.152 25.595 2.769  5.439  1.448  H44 GN9 86 
GN9 H45 H45 H 0 1 N N N N N N 140.481 36.861 26.165 4.492  4.998  1.376  H45 GN9 87 
GN9 H47 H47 H 0 1 N N N N N N 138.102 34.248 30.339 7.419  0.539  2.019  H47 GN9 88 
GN9 H48 H48 H 0 1 N N N N N N 139.589 35.034 30.967 9.073  -0.083 2.233  H48 GN9 89 
GN9 H49 H49 H 0 1 N N N N N N 139.710 33.767 29.699 8.600  0.682  0.696  H49 GN9 90 
GN9 H50 H50 H 0 1 N N N N N N 138.516 32.692 33.598 6.919  -3.024 1.658  H50 GN9 91 
GN9 H51 H51 H 0 1 N N N N N N 138.810 34.420 33.203 8.163  -2.368 2.750  H51 GN9 92 
GN9 H52 H52 H 0 1 N N N N N N 137.393 33.566 32.502 6.568  -1.584 2.644  H52 GN9 93 
GN9 H53 H53 H 0 1 N N N N N N 141.001 32.927 36.553 7.990  -5.306 -1.620 H53 GN9 94 
GN9 H54 H54 H 0 1 N N N N N N 139.545 32.779 35.512 6.669  -5.182 -0.434 H54 GN9 95 
GN9 H55 H55 H 0 1 N N N N N N 140.498 31.317 35.935 6.400  -4.683 -2.121 H55 GN9 96 
# 
loop_
_chem_comp_bond.comp_id 
_chem_comp_bond.atom_id_1 
_chem_comp_bond.atom_id_2 
_chem_comp_bond.value_order 
_chem_comp_bond.pdbx_aromatic_flag 
_chem_comp_bond.pdbx_stereo_config 
_chem_comp_bond.pdbx_ordinal 
GN9 O3  C17 DOUB N N 1  
GN9 O4  C22 DOUB N N 2  
GN9 C20 C18 SING N N 3  
GN9 C20 C21 SING N N 4  
GN9 C18 C19 SING N N 5  
GN9 C18 N1  SING N N 6  
GN9 C9  C8  SING N N 7  
GN9 C10 C8  SING N N 8  
GN9 C17 N1  SING N N 9  
GN9 C17 C12 SING N N 10 
GN9 C22 C21 SING N N 11 
GN9 C22 N2  SING N N 12 
GN9 C16 C14 SING N N 13 
GN9 C13 C12 SING N N 14 
GN9 C13 C14 SING N N 15 
GN9 C28 C23 SING N N 16 
GN9 C8  C7  SING N N 17 
GN9 C23 N2  SING N N 18 
GN9 C23 C24 SING N N 19 
GN9 C12 N   SING N N 20 
GN9 N   C11 SING N N 21 
GN9 C14 C15 SING N N 22 
GN9 N2  C26 SING N N 23 
GN9 C7  C6  SING N N 24 
GN9 C27 O6  SING N N 25 
GN9 C11 C6  SING N N 26 
GN9 C11 O2  DOUB N N 27 
GN9 C6  O1  SING N N 28 
GN9 C24 O6  SING N N 29 
GN9 C24 C25 DOUB N N 30 
GN9 C26 O5  DOUB N N 31 
GN9 C26 C25 SING N N 32 
GN9 O1  C5  SING N N 33 
GN9 O   C5  DOUB N N 34 
GN9 C30 N3  SING N N 35 
GN9 C5  C4  SING N N 36 
GN9 N3  C4  SING N N 37 
GN9 N3  C29 SING N N 38 
GN9 C4  C2  SING N N 39 
GN9 C3  C2  SING N N 40 
GN9 C2  C1  SING N N 41 
GN9 C1  C   SING N N 42 
GN9 C1  H1  SING N N 43 
GN9 C1  H2  SING N N 44 
GN9 C2  H3  SING N N 45 
GN9 C3  H4  SING N N 46 
GN9 C3  H5  SING N N 47 
GN9 C3  H6  SING N N 48 
GN9 C4  H7  SING N N 49 
GN9 C6  H8  SING N N 50 
GN9 C25 H9  SING N N 51 
GN9 C27 H10 SING N N 52 
GN9 C27 H11 SING N N 53 
GN9 C27 H12 SING N N 54 
GN9 C23 H13 SING N N 55 
GN9 C28 H14 SING N N 56 
GN9 C28 H15 SING N N 57 
GN9 C28 H16 SING N N 58 
GN9 C21 H17 SING N N 59 
GN9 C21 H18 SING N N 60 
GN9 C20 H19 SING N N 61 
GN9 C20 H20 SING N N 62 
GN9 C18 H21 SING N N 63 
GN9 C19 H22 SING N N 64 
GN9 C19 H23 SING N N 65 
GN9 C19 H24 SING N N 66 
GN9 N1  H25 SING N N 67 
GN9 C12 H26 SING N N 68 
GN9 C13 H27 SING N N 69 
GN9 C13 H28 SING N N 70 
GN9 C14 H29 SING N N 71 
GN9 C16 H30 SING N N 72 
GN9 C16 H31 SING N N 73 
GN9 C16 H32 SING N N 74 
GN9 C15 H33 SING N N 75 
GN9 C15 H34 SING N N 76 
GN9 C15 H35 SING N N 77 
GN9 N   H36 SING N N 78 
GN9 C7  H37 SING N N 79 
GN9 C7  H38 SING N N 80 
GN9 C8  H39 SING N N 81 
GN9 C10 H40 SING N N 82 
GN9 C10 H41 SING N N 83 
GN9 C10 H42 SING N N 84 
GN9 C9  H43 SING N N 85 
GN9 C9  H44 SING N N 86 
GN9 C9  H45 SING N N 87 
GN9 C30 H47 SING N N 88 
GN9 C30 H48 SING N N 89 
GN9 C30 H49 SING N N 90 
GN9 C29 H50 SING N N 91 
GN9 C29 H51 SING N N 92 
GN9 C29 H52 SING N N 93 
GN9 C   H53 SING N N 94 
GN9 C   H54 SING N N 95 
GN9 C   H55 SING N N 96 
# 
loop_
_pdbx_chem_comp_descriptor.comp_id 
_pdbx_chem_comp_descriptor.type 
_pdbx_chem_comp_descriptor.program 
_pdbx_chem_comp_descriptor.program_version 
_pdbx_chem_comp_descriptor.descriptor 
GN9 SMILES           ACDLabs              12.01 "C(C)C(C)C(C(OC(C(=O)NC(C(=O)NC(CCC(=O)N1C(=O)C=C(OC)C1C)C)CC(C)C)CC(C)C)=O)N(C)C"                                                                                                                                            
GN9 InChI            InChI                1.03  "InChI=1S/C31H54N4O7/c1-12-20(6)28(34(9)10)31(40)42-25(16-19(4)5)30(39)33-23(15-18(2)3)29(38)32-21(7)13-14-26(36)35-22(8)24(41-11)17-27(35)37/h17-23,25,28H,12-16H2,1-11H3,(H,32,38)(H,33,39)/t20-,21-,22-,23-,25-,28-/m0/s1" 
GN9 InChIKey         InChI                1.03  KQLKGAFEYUEPPA-ISUPFBBGSA-N                                                                                                                                                                                                   
GN9 SMILES_CANONICAL CACTVS               3.385 "CC[C@H](C)[C@H](N(C)C)C(=O)O[C@@H](CC(C)C)C(=O)N[C@@H](CC(C)C)C(=O)N[C@@H](C)CCC(=O)N1[C@@H](C)C(=CC1=O)OC"                                                                                                                  
GN9 SMILES           CACTVS               3.385 "CC[CH](C)[CH](N(C)C)C(=O)O[CH](CC(C)C)C(=O)N[CH](CC(C)C)C(=O)N[CH](C)CCC(=O)N1[CH](C)C(=CC1=O)OC"                                                                                                                            
GN9 SMILES_CANONICAL "OpenEye OEToolkits" 2.0.7 "CC[C@H](C)[C@@H](C(=O)O[C@@H](CC(C)C)C(=O)N[C@@H](CC(C)C)C(=O)N[C@@H](C)CCC(=O)N1[C@H](C(=CC1=O)OC)C)N(C)C"                                                                                                                  
GN9 SMILES           "OpenEye OEToolkits" 2.0.7 "CCC(C)C(C(=O)OC(CC(C)C)C(=O)NC(CC(C)C)C(=O)NC(C)CCC(=O)N1C(C(=CC1=O)OC)C)N(C)C"                                                                                                                                              
# 
loop_
_pdbx_chem_comp_identifier.comp_id 
_pdbx_chem_comp_identifier.type 
_pdbx_chem_comp_identifier.program 
_pdbx_chem_comp_identifier.program_version 
_pdbx_chem_comp_identifier.identifier 
GN9 "SYSTEMATIC NAME" ACDLabs              12.01 "(2S)-1-{[(2S)-1-({(2S)-5-[(2S)-3-methoxy-2-methyl-5-oxo-2,5-dihydro-1H-pyrrol-1-yl]-5-oxopentan-2-yl}amino)-4-methyl-1-oxopentan-2-yl]amino}-4-methyl-1-oxopentan-2-yl N,N-dimethyl-L-isoleucinate"                                                                         
GN9 "SYSTEMATIC NAME" "OpenEye OEToolkits" 2.0.7 "[(2~{S})-1-[[(2~{S})-1-[[(2~{S})-5-[(2~{S})-3-methoxy-2-methyl-5-oxidanylidene-2~{H}-pyrrol-1-yl]-5-oxidanylidene-pentan-2-yl]amino]-4-methyl-1-oxidanylidene-pentan-2-yl]amino]-4-methyl-1-oxidanylidene-pentan-2-yl] (2~{S},3~{S})-2-(dimethylamino)-3-methyl-pentanoate" 
# 
_pdbx_chem_comp_synonyms.ordinal      1 
_pdbx_chem_comp_synonyms.comp_id      GN9 
_pdbx_chem_comp_synonyms.name         "(2S)-1-{[(2S)-1-({(2S)-5-[(2S)-3-methoxy-2-methyl-5-oxo-2,5-dihydro-1H-pyrrol-1-yl]-5-oxopentan-2-yl}amino)-4-methyl-1-oxopentan-2-yl]amino}-4-methyl-1-oxopentan-2-yl N,N-dimethyl-L-isoleucinate" 
_pdbx_chem_comp_synonyms.provenance   PDB 
_pdbx_chem_comp_synonyms.type         ? 
# 
loop_
_pdbx_chem_comp_audit.comp_id 
_pdbx_chem_comp_audit.action_type 
_pdbx_chem_comp_audit.date 
_pdbx_chem_comp_audit.processing_site 
GN9 "Create component"         2020-08-30 RCSB 
GN9 "Modify leaving atom flag" 2020-08-31 RCSB 
GN9 "Modify synonyms"          2021-03-13 RCSB 
GN9 "Initial release"          2021-08-25 RCSB 
GN9 "Modify PCM"               2024-09-27 PDBE 
# 
_pdbx_chem_comp_pcm.pcm_id                             1 
_pdbx_chem_comp_pcm.comp_id                            GN9 
_pdbx_chem_comp_pcm.modified_residue_id                CYS 
_pdbx_chem_comp_pcm.type                               None 
_pdbx_chem_comp_pcm.category                           "Covalent chemical modification" 
_pdbx_chem_comp_pcm.position                           "Amino-acid side chain" 
_pdbx_chem_comp_pcm.polypeptide_position               "Any position" 
_pdbx_chem_comp_pcm.comp_id_linking_atom               C20 
_pdbx_chem_comp_pcm.modified_residue_id_linking_atom   SG 
_pdbx_chem_comp_pcm.uniprot_specific_ptm_accession     ? 
_pdbx_chem_comp_pcm.uniprot_generic_ptm_accession      ? 
# 
